Type session in to the ligolo UI, select the correct machine, then type ifconfig. Find the correct network, and add the route with the following, OUTSIDE LIGOLO:
sudo ip route add 192.168.0.0/24 dev ligolo
Now, simply type start in to the ligolo UI to start the tunnel. You can now access the network without using proxychains (for example with the above network, you can now ping 192.168.0.123, where you couldnt before.)